2-trans,6-trans-farnesol is shown to be a precursor in the biosynthesis of dendrobine rather than the 2-cis, 6-trans-isomer; the 1-pro-R hydrogen of farnesol is involved in a 1,3-shift in the early stages of the pathway.
A. Corbella, P. Gariboldi, G. Jommi and M. Sisti, J. Chem. Soc., Chem. Commun., 1975, 288 DOI: 10.1039/C39750000288
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