Tris(o-dimethylarsinophenyl)bismuthine (bitas) forms the square pyramidal complexes [Ni(bitas)X]BPh4(X = halide), the first examples of trivalent bismuth co-ordinated to a 3d transition metal in a positive oxidation state, and [Ni2(bitas)3]4+, which contains examples of bitas functioning as a tridentate and a tetra-dentate ligand.
W. Levason, C. A. McAuliffe and S. G. Murray, J. Chem. Soc., Chem. Commun., 1975, 164 DOI: 10.1039/C39750000164
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