Plane-polarized light has been used to produce oriented [Cr(CO)5] in CH4 matrices, the symmetry of the 489nm transition of [Cr(CO)5] is determined, and photo-orientation is demonstrated for the first time.
J. K. Burdett, R. N. Perutz, M. Poliakoff and J. J. Turner, J. Chem. Soc., Chem. Commun., 1975, 157 DOI: 10.1039/C39750000157
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