SCHEDULED MAINTENANCE
The ultra-violet and visible spectra of 19 transition metal ions have been examined within the framework of j-j theory. For each ion the Racah parameters B and C, and the Trees correction and spin-orbit coupling constants were calculated. The agreement with experiment was very close, a typical deviation being about 14 cm–1. Some of the published assignments are questioned and some earlier suggestions are found to be in error.
J. J. P. Stewart, J. Chem. Soc., Faraday Trans. 2, 1974, 70, 1882 DOI: 10.1039/F29747001882
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