Secondary electron capture by (π-methyl benzoate)tricarbonylchromium yields a molecular anion which undergoes decarbonylation and further loss of three CO groups; in addition, Cr– ions have been identified in the 70 eV negative ion mass spectrum of this compound.
M. R. Blake, I. W. Fraser, J. L. Garnett, I. K. Gregor and R. Levot, J. Chem. Soc., Chem. Commun., 1974, 1004 DOI: 10.1039/C39740001004
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