Tri-isopropylmethyl is one of the most stable aliphatic hydrocarbnon radicals known, and displays an e.s.r. spectrum indicative of an sp2 hybridization with the three β-hydrogens symmetrically aligned in the plane orthogonal to the p-orbital containing the unpaired electron.
D. Griller, S. Içli, C. Thankachan and T. T. Tidwell, J. Chem. Soc., Chem. Commun., 1974, 913 DOI: 10.1039/C39740000913
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