Correlation of the logarithms of the ratios of cis to trans diols formed in the acid-catalysed hydrolysis of 13 1-arylcyclohexene oxides with the σ+ constants indicates that there is a higher degree of carbocationic character in the transition state leading to the cis-product.
C. Battistini, A. Balsamo, G. Berti, P. Crotti, B. Macchia and F. Macchia, J. Chem. Soc., Chem. Commun., 1974, 712 DOI: 10.1039/C39740000712
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