The 1J(PP) n.m.r. couplings obtained for (PCF3)5 are compared with the values previously obtained for (PMe)5 and the results are discussed in terms of bond orientation and substituent effects.
J. P. Albrand and J. B. Robert, J. Chem. Soc., Chem. Commun., 1974, 644 DOI: 10.1039/C39740000644
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