Phosphoranyl radicals with an aryl ligand appear to have a relatively small phosphorus doublet splitting constant, indicating a relation between the aP and the structure of these radicals.
G. Boekestein, E. H. J. M. Jansen and H. M. Buck, J. Chem. Soc., Chem. Commun., 1974, 118 DOI: 10.1039/C39740000118
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