The general-base catalyzed ionization of phenyl-nitromethane is subject to large primary kinetic hydrogen isotope effects; these effects, their activation parameters, and the Brønsted catalysis coefficient for the reaction are used to discuss possible transition-state structures.
J. R. Keefe and N. H. Munderloh, J. Chem. Soc., Chem. Commun., 1974, 17 DOI: 10.1039/C39740000017
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