Photoelectron spectroscopic data for amino- and oxy-benzenes are discussed in terms of a simple p-π interaction scheme. Steric hindrance is shown only to be important in ortho substituted NN-dialkylanilines and in 2,6-dimethylanisole. In the nitrogen series there is indication that the N atom is not planar.
J. P. Maier and D. W. Turner, J. Chem. Soc., Faraday Trans. 2, 1973, 69, 521 DOI: 10.1039/F29736900521
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