A calorimetric study of the reaction between bromine and Co2(CO)8 in carbon tetrachloride gave ΔH10[Co2(CO)8(c)]298 =–298·85± 1·1 kcal mol–1 from which an estimate of 33 kcal for the mean cobalt–carbon monoxide bond dissociation energy is derived.
A. Cartner, B. Robinson and P. J. Gardner, J. Chem. Soc., Chem. Commun., 1973, 317b DOI: 10.1039/C3973000317B
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