Cystinylvaline and cysteinyldehydrovaline derivatives have been oxidised to isothiazolidinones, a new group of peptide derivatives; a chemically reasonable scheme for the biosynthesis of β-lactam antibiotics is presented.
J. E. Baldwin, S. B. Haber and J. Kitchin, J. Chem. Soc., Chem. Commun., 1973, 790 DOI: 10.1039/C39730000790
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