The first stable adduct from a nucleophile, potassium methoxide, and a deativated cycloheptatrienone, 2-methoxytropone, has a flattened gem-dialkoxy-structure, whilst adducts at an unsubsititued carbon, such as those from methoxide with tropone, are short-lived species.
G. Biggi, C. A. Veracini and F. Pietra, J. Chem. Soc., Chem. Commun., 1973, 523 DOI: 10.1039/C39730000523
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