Issue 10, 1973

Ab initio calculations on the electrocyclic transformation of the cyclopropyl radical to the allyl radical

Abstract

Ab initio calculations indicate that the ring-opening of the cyclopropyl radical is formally forbidden in both the conrotatory and disrotatory modes, but that if distortion of the molecule occurs a near-disrotatory reaction would be preferred.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 334-335

Ab initio calculations on the electrocyclic transformation of the cyclopropyl radical to the allyl radical

L. Farnell and W. G. Richards, J. Chem. Soc., Chem. Commun., 1973, 334 DOI: 10.1039/C39730000334

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