It has proved possible to observe n.m.r.spectra from deuterium nuclei occurning in natural abundance; the observation of small chemical-shift differences, referred to 2H in Me4Si, is facilitated by proton noise decoupling.
J. M. Briggs, L. F. Farnell and E. W. Randall, J. Chem. Soc., Chem. Commun., 1973, 70 DOI: 10.1039/C39730000070
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