Issue 0, 1972

Flavofungin: a mixture of 13,15,17,19,21,23,25,27-octahydroxy-31-isopropyl-14-methyl- and 13,15,17,19,21,23,25,27-octahydroxy-14-methyl-31-s-butyl-hentriaconta-2,4,6,8,10,28-hexaen-31-olide

Abstract

Flavofungin, the antifungal antibiotic from Streptomyces flavofungini, has been shown to be a mixture (ca. 10:1) of 13,15,17,19,21,23,25,27-octahydroxy-31-isopropyl-14-methyl-(1a) and 13,15,17,19,21,23,25,27-octahydroxy-14-methyl-31-s-butyl-(1b) hentriaconta-2,4,6,8,10,23-hexaen-31-olide. Its relationship to mycoticin is discussed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 1848-1856

Flavofungin: a mixture of 13,15,17,19,21,23,25,27-octahydroxy-31-isopropyl-14-methyl- and 13,15,17,19,21,23,25,27-octahydroxy-14-methyl-31-s-butyl-hentriaconta-2,4,6,8,10,28-hexaen-31-olide

R. Bognár, S. Makleit, K. Zsupán, B. O. Brown, W. J. S. Lockley, T. P. Toube and B. C. L. Weedon, J. Chem. Soc., Perkin Trans. 1, 1972, 1848 DOI: 10.1039/P19720001848

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