Three preparations of the compounds Na4TiO4 and Na2ZrO3 are described and their formulae confirmed by thermogravimetric analysis. The X-ray diffraction pattern of Na4TiO4 is indexed as orthorhombic with cell dimensions a= 11·607, b= 13·610, and c= 9·693 Å, and the compound appears to be one member of an isostructural series of compounds.
M. G. Barker and D. J. Wood, J. Chem. Soc., Dalton Trans., 1972, 2448 DOI: 10.1039/DT9720002448
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