Issue 11, 1972

Structural studies on co-ordinated macrocyclic ligands. Part I. Crystal and molecular structure of [(1RS,3SR,8RS,10SR)-3,5,7,7,10,12,-14,14-octamethyl-1,4,8,11-tetra-azacyclotetradeca-4,11-diene]nickel(II) perchlorate

Abstract

The X-ray structural analysis of the title compound has been determined from diffractometer data and refined by least-squares to R 0·08 for 2211 independent reflexions. Crystals are monoclinic, space-group P21/c, a= 16·401(4), b= 10·856(6), c= 15·072(4)Å,β= 91·07(3)°, Z= 4. In the complex cation the two secondary amine and two imino-donor groups are in trans planar co-ordination. The two asymmetric carbon centres and the two asymmetric nitrogen centres occur in racemic pairs, the configuration of the racemate being (1RS, 3SR, 8RS, 10SR).

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1115-1120

Structural studies on co-ordinated macrocyclic ligands. Part I. Crystal and molecular structure of [(1RS,3SR,8RS,10SR)-3,5,7,7,10,12,-14,14-octamethyl-1,4,8,11-tetra-azacyclotetradeca-4,11-diene]nickel(II) perchlorate

D. A. Swann, T. N. Waters and N. F. Curtis, J. Chem. Soc., Dalton Trans., 1972, 1115 DOI: 10.1039/DT9720001115

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