Benzaldehyde when irradiated in benzene yielded almost equal amounts of benzoin (I), deoxybenzoin (II), and 1,2-diphenylethane-1,2-diol (III); in ethanol the main product was (III) with only a trace of (I); while in hex-1-yne, seven isolable products were (I), (II), (III), heptanophenone (IV), cis-hept-2-eno-phenone (V), trans-hept-2-enophenone (VI), and 2-n-butyl-1,4-diphenylbutane-1,4-dione (VII).
J. S. Bradshaw, R. D. Knudsen and W. W. Parish, J. Chem. Soc., Chem. Commun., 1972, 1321 DOI: 10.1039/C39720001321
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