Ergosterol peroxide (ep), synthetic or from fungal extracts, is shown to be a mixture of isomers arising from α- and β-attack by O2(1Δg) on ergosterol; the stereochemistry of the peroxide bridge is assigned.
J. Arditti, R. E. M. H. Fisch and B. H. Flick, J. Chem. Soc., Chem. Commun., 1972, 1217 DOI: 10.1039/C39720001217
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