Issue 22, 1972

Mechanism of the formation of semiquinone radicals by ultra-violet irradiation of six-membered aromatic aza-compounds in neutral methanol, and of radical cations by ultra-violet irradiation of six-membered aromatic diaza-compounds in methanol acidified with hydrochloric acid

Abstract

9-Phenylacridine and quinoxaline react with methanol but do not directly abstract a hydrogen radical from the solvent; in methanol–HCl, pyrazine, quinoxaline, and phenazine give radical cations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1207-1208

Mechanism of the formation of semiquinone radicals by ultra-violet irradiation of six-membered aromatic aza-compounds in neutral methanol, and of radical cations by ultra-violet irradiation of six-membered aromatic diaza-compounds in methanol acidified with hydrochloric acid

A. Castellano, J. Catteau and A. Lablache–Combier, J. Chem. Soc., Chem. Commun., 1972, 1207 DOI: 10.1039/C39720001207

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