Effects of the geometrical restrictions on intramolecular exciplex formation have been studied for some systems containing anthracene or pyrene and NN-dimethylaniline moieties, and it is concluded that a parallel sandwich structure may be favourable but not necessary for intra- and inter-molecular exciplex formation.
R. Ide, Y. Sakata, S. Misumi, T. Okada and N. Mataga, J. Chem. Soc., Chem. Commun., 1972, 1009 DOI: 10.1039/C39720001009
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