SCHEDULED MAINTENANCE
Reaction of CpMo(CO)3– and ClCSNMe2 yields CpMo(CO)2CSNMe2 which gives [CpMo(CO)2C(SMe)NMe2]+(isolated eventually as the PF6– salt) with [Me3O]BF4; the same reactions are reported with Mn(CO)4PPh3–; the structures of these complexes are believed to involve the C–S group as a bidentate three electron donor.
P. M. Treichel and W. K. Dean, J. Chem. Soc., Chem. Commun., 1972, 804 DOI: 10.1039/C39720000804
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