The reaction of 2-methoxyallyl chloride (1a) and nonacarbonyldi-iron affords 3-methoxybuta-1,3-dienone(tricarbonyl)iron (4), while the corresponding bromide (1b) and iodide (1c) form the π-allyl complexes (2b) and (2c), respectively; 2-methoxy-π-allyl(tricarbonyl)iron chloride (2a) can be obtained from 1-chloro-2-methoxypropene (3a) and nonacarbonyldi-iron.
A. E. Hill and H. M. R. Hoffmann, J. Chem. Soc., Chem. Commun., 1972, 574 DOI: 10.1039/C39720000574
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