The first spectral observation of intermediates in the transition metal-catalysed rearrangement of bicyclobutanes strongly supports the proposed intervention of an unstable carbene–palladium complex.
S. Masamune, M. Sakai and N. Darby, J. Chem. Soc., Chem. Commun., 1972, 471 DOI: 10.1039/C39720000471
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