S-Methyl-S-(3,3-dimethylallyl)carbene, generated by Bamford–Stevens reaction of the corresponding toluene-p-sulphonylhydrazone, undergoes a 2,3-sigmatropic rearrangement to a dithiocarboxylic acid ester, thereby providing a new carbon–carbon bond synthesis.
J. E. Baldwin and J. A. Walker, J. Chem. Soc., Chem. Commun., 1972, 354 DOI: 10.1039/C39720000354
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