Issue 2, 1972

A rapid rearrangement of α-bromoethylborane induced by electrophilic reagents

Abstract

α-Bromoethyldiethylborane undergoes rapid almost instantaneous, rearrangement at 25 °C to s-butyl ethylboron bromide under the influence of aluminium bromide and related electrophilic catalysts.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 71-72

A rapid rearrangement of α-bromoethylborane induced by electrophilic reagents

H. C. Brown and Y. Yamamoto, J. Chem. Soc., Chem. Commun., 1972, 71 DOI: 10.1039/C39720000071

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