Volume 67, 1971
From the journal:

Transactions of the Faraday Society

Isotopic exchange and ion association of some rhodium III and iridium III chloro amine complexes in aqueous solution

K. W. Bowker,   E. R. Gardner  and  J. Burgess  

Abstract

The effect of chloride ion concentration, complex concentration and hydrogen ion concentration on the rate of exchange of chlorine-36 with cis-[Iren2Cl2]Cl, trans-[Rhen2Cl2]Cl and cis-[RhtrienCl2]Cl was studied and the results explained in terms of ion-pair formation. In addition, the rate of exchange of cis-[Iren2Cl]Cl and cis-[Rhtrien Cl2]Cl with chlorine-36 was measured over a range of temperatures and the activation energies for the reactions determined.

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Article information

DOI
https://doi.org/10.1039/TF9716703076
Article type
Paper

Trans. Faraday Soc., 1971,67, 3076-3080

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Isotopic exchange and ion association of some rhodium III and iridium III chloro amine complexes in aqueous solution

K. W. Bowker, E. R. Gardner and J. Burgess, Trans. Faraday Soc., 1971, 67, 3076 DOI: 10.1039/TF9716703076

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