Volume 67, 1971

Infra-red chemiluminescence from vibrationally excited CO. Part 1.—The reaction of atomic oxygen with carbon disulphide

Abstract

Infra-red chemiluminescence from the reaction between atomic oxygen and carbon disulphide arises almost entirely from vibrationally excited CO. Evidence is presented which demonstrates conclusively that CO is excited in the reaction; O + CS →CO + S; the rate constant for this reaction at room temperature is estimated to be 1.4 × 10–11 cm3 molecule–1 s–1.

Article information

Article type
Paper

Trans. Faraday Soc., 1971,67, 2586-2597

Infra-red chemiluminescence from vibrationally excited CO. Part 1.—The reaction of atomic oxygen with carbon disulphide

G. Hancock and I. W. M. Smith, Trans. Faraday Soc., 1971, 67, 2586 DOI: 10.1039/TF9716702586

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