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The barrier to internal rotation in N-methylformamide and N-methylacetamide has been shown to be comparable to those in NN-dimethylamides, by n.m.r. lineshape analysis of the N-methyl signals.
T. Drakenberg and S. Forsén, J. Chem. Soc. D, 1971, 1404 DOI: 10.1039/C29710001404
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