The chiroptical properties of steroidal βγ-unsaturated sulphoxides are determined by the relative spatial orientation of the olefinic double bond and the lone electron pair on sulphur, and chirality at sulphur does not necessarily play a predominant role.
D. N. Jones, E. E. Helmy, R. J. K. Taylor and A. C. F. Edmonds, J. Chem. Soc. D, 1971, 1401 DOI: 10.1039/C29710001401
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