Ru(CO)2(CNR)(PPh3)2, Ru(CO)(CNR)(PPh3)3, and the dioxygen complex Ru(O2)(CO)(CNR)(PPh3)2, (R =p-tolyl) have been prepared by the action of bases on [RuH(CO)2(CNR)(PPh3)2]+ and [RuH(CO)(CNR)-(PPh3)3]+; protonation of Ru(CO)2(CNR)(PPh3)2 occurs specifically trans to isocyanide.
D. F. Christian and W. R. Roper, J. Chem. Soc. D, 1971, 1271 DOI: 10.1039/C29710001271
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