Tetrafluoroethylene and hexafluoropropene react with Fe(CO)3(diene)(diene = buta-1,3-diene, isoprene, or cinnamaldehyde) or tricarbonyl(trimethylenemethane)-iron to form π-allylic complexes, in which the iron atom and the allyl group are linked by a fluorocarbon chain; treatment of [[graphic omitted](CO)2π-C4Me4] with trimethyl phosphite leads to a similar linking reaction.
A. Bond, M. Green, B. Lewis and S. F. W. Lowrie, J. Chem. Soc. D, 1971, 1230 DOI: 10.1039/C29710001230
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