2-Diphenylphosphinylethyl cations, generated in a variety of ways, rearrange by diphenylphosphinyl migration, even when the resulting cation has an identical structure to the unrearranged cation.
P. F. Cann, D. Howells and S. Warren, J. Chem. Soc. D, 1971, 1148 DOI: 10.1039/C29710001148
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