Bis(trifluoromethyl)diazomethane reacts with zerovalent Ni, Pd, or Pt complexes to afford compounds L2[graphic omitted]·N : C(CF3)2(M = Ni, L = ButNC or PPh3, L2= 1,5-C8H12; M = Pd, L = ButNC or C6H11NC; M = Pt, L = PPh3); the structure of the platinum complex was established by a single crystal X-ray diffraction study.
J. Clemens, R. E. Davis, M. Green, J. D. Oliver and F. G. A. Stone, J. Chem. Soc. D, 1971, 1095 DOI: 10.1039/C29710001095
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