Issue 9, 1971

A simple synthetic route to d8 complexes of rhodium and iridium. An electronegativity scale for anionic ligands

Abstract

Molecular fluoro-complexes trans-[MF(CO)(Ph3P)2](M = Ir, Rh), undergo rapid substitution reactions to yield a variety of new derivatives, trans-[MA(CO)(Ph3P)2](A = univalent anionic ligand); a relation between the νCO and “total electronegativity” of A in these compounds is suggested.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 418-419

A simple synthetic route to d8 complexes of rhodium and iridium. An electronegativity scale for anionic ligands

L. Vaska and J. Peone, J. Chem. Soc. D, 1971, 418 DOI: 10.1039/C29710000418

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