The reactions of trifluoromethyl radicals with silane, trimethylsilane and tetramethylsilane have been studied in the gas phase. Arrhenius parameters (based on a value of 1013.36 mol–1 cm3 s–1 for the velocity constant for the combination of trifluoromethyl radicals) have been measured or estimated for the following reactions: [graphic ommitted].
E. R. Morris and J. C. J. Thynne, Trans. Faraday Soc., 1970, 66, 183 DOI: 10.1039/TF9706600183
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