Measurements of the volume changes which accompany the wetting of Graphon by n-alkanes, benzene and water, and the heats of wetting for the same systems, are analyzed. For the long-chain alkanes there is evidence for a pre-freezing phenomenon near the Graphon/liquid interface. For liquids composed of smaller molecules this effect is not found.
S. G. Ash and G. H. Findenegg, Spec. Discuss. Faraday Soc., 1970, 1, 105 DOI: 10.1039/SD9700100105
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