2-Imino-1,4-benzodioxan has been prepared and shows no evidence of being in equilibrium with its tautomer (o-acetoxyphenoxy)acetonitrile either in the solid state or in solution in dimethyl sulphoxide. Acetylation of this compound with acetic anhydride is accompanied by trimerisation to give 2,4,6-tris-(o-acetoxyphenoxymethyl)-1,3,5-triazine.
A. W. Archer and P. A. Claret, J. Chem. Soc. C, 1970, 1296 DOI: 10.1039/J39700001296
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