The tridentate ligand 2-methyl-8-[(6-methyl-2-pyridyl)methyleneamino]quinoline (mpq) forms high-spin five-co-ordinate complexes with nickel(II) and copper(II) of the type [M(mpq)X2], xH2O (X = Cl, Br, I, NO3, or ClO4), for which a trigonal bipyramidal structure is proposed. Analytical, spectral, and conductivity data support this assignment.
M. R. Litzow, L. F. Power and A. M. Tait, J. Chem. Soc. A, 1970, 2907 DOI: 10.1039/J19700002907
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