The magnitude of the extinction coefficient and the shift on substitution show that the band at 16,200 cm–1 in the absorption spectrum of Fe(C5H5)2+, which formerly was attributed to a 3d–3d ligand-field transition, is due to a ligand-to-metal e1u→e2g charge-transfer transition.
R. Prins, J. Chem. Soc. D, 1970, 280b DOI: 10.1039/C2970000280B
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