Issue 22, 1970

Hydrogen transfer from HCl to the nitrosyl ligand. Examples of co-ordinated HNO, NHOH-, and NH2OH

Abstract

The nitrosyl complexes, OsCl(CO)(NO)(PPh3)2, Os(NO)2(PPh3)2, and Ir(NO)(PPh3)3 react reversibly with one, two, and three moles of HCl, respectively, forming OsCl2(CO)(HNO)(PPh3)2, OsCl2(NHOH)(NO)(PPh3)2, and IrCl3(NH2OH)(PPh3)2.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1501-1502

Hydrogen transfer from HCl to the nitrosyl ligand. Examples of co-ordinated HNO, NHOH-, and NH2OH

K. R. Grundy, C. A. Reed and W. R. Roper, J. Chem. Soc. D, 1970, 1501 DOI: 10.1039/C29700001501

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