d-Orbital participation in the bonding in molecules containing phosphorus, sulphur, and chlorine studied by ab initio SCF–MO calculations
Abstract
d-Orbital participation in the bonding in molecules containing phosphorus, sulphur, and chlorine is discussed with the aid of ab initio SCF–MO calculations on ClO2–, ClO3–, ClO4–, PF3O, SO2F2, and ClO3F.