The reactions of NOPF6 in acetonitrile with (π-PhMe)Cr(CO)3 and M2(CO)10(M = Mn and Re) lead to the formation of [Cr(NO)2(MeCN)4][PF6]2 and [M(CO)5(MeCN)][PF6], respectively, which are valuable new organometallic reagents as exemplified by a variety of reactions.
N. G. Connelly and L. F. Dahl, J. Chem. Soc. D, 1970, 880 DOI: 10.1039/C29700000880
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