The exchange of the methylene-group protons of amino-acid or peptide complexes of copper(II) or cobalt(III) has been investigated and is shown in general to be stereoselective and to occur only for the C-terminal residue of the peptides.
R. D. Gillard and D. A. Phipps, J. Chem. Soc. D, 1970, 800 DOI: 10.1039/C29700000800
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