Reactions of cyclododeca-1,5,9-trienes with Ru3(CO)12 lead to dehydrogenation and isomerisation with the formation of four cluster complexes: in the major product, HRu3(CO)9(C12H15), the monocyclic ligand is attached to the cluster by an unusual allylic bonding arrangement involving only three carbon atoms.
M. I. Bruce, M. A. Cairns, A. Cox, M. Green, M. D. H. Smith and P. Woodward, J. Chem. Soc. D, 1970, 735 DOI: 10.1039/C29700000735
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