The absolute stereochemistry of trisporic acid C (1) is 1S, 13R; the 1α-methyl, which is equatorial, is selectively labelled by [2-14C]mevalonate, and corresponding chirality at C-1 in [2-14C]mevalonate-labelled β-carotene is thereby indicated with implications for the stereochemistry of cyclization in β-carotene biosynthesis.
J. D. Bu'Lock, D. J. Austin, G. Snatzke and L. Hruban, J. Chem. Soc. D, 1970, 255 DOI: 10.1039/C29700000255
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