Autoxidation of 4-alkyl-2,6-di-t-butylphenols (III) with di-(3-salicylideneaminopropyl)aminecobalt(II) catalyst in methanol gives the corresponding quinols, 4-alkyl-2,6-di-t-butyl-4-hydroxycyclohexa-2,5-dienones (IV), which are formed via the corresponding hydroperoxides (V).
T. Matsuura, K. Watanabe and A. Nishinaga, J. Chem. Soc. D, 1970, 163 DOI: 10.1039/C29700000163
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