Steroidal selenoxides have been separated chromatographically into diastereoisomers at selenium, and their mode of elimination permitted allocations of configuration at selenium; their chiroptical properties were similar to those of related sulphoxides.
D. N. Jones, D. Mundy and R. D. Whitehouse, J. Chem. Soc. D, 1970, 86 DOI: 10.1039/C29700000086
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